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Tuning the Bonding of a μ-Mesityl Ligand on Dicopper(I) through a Proton-Responsive Expanded PNNP Pincer Ligand

preprint
submitted on 27.11.2019 and posted on 04.12.2019 by Errikos Kounalis, Martin Lutz, Daniël Broere

We report the synthesis and characterization of a series of cationic, neutral and anionic dicopper(I) complexes featuring a µ-mesityl ligand and a naphthyridine-derived PNNP expanded pincer ligand. Structural characterization showed that the protonation state of the dinucleating ligand has a pronounced effect on the bending and tilting of the µ-mesityl ligand. DFT calculations indicate that the varying orientations of the µ-mesityl ligand are inherent due to changes in electronic structure rather than crystal packing effects. NBO analysis reveals how the interactions that contribute to the 3-center 2-electron bond between the µ-mesityl ligand and the dicopper core change for the various degrees of observed bending and tilting.

Funding

NWO START-UP grant 740.018.019 to D.L.J.B.

European Union's Horizon 2020 research and innovation program (agreement 840836, MSCA-IF to D.L.J.B., BiMetaCat).

History

Email Address of Submitting Author

d.l.j.broere@uu.nl

Institution

Utrecht University

Country

The Netherlands

ORCID For Submitting Author

0000-0002-6641-4092

Declaration of Conflict of Interest

None

Version Notes

First version

Exports