Tuning Iridium(I) PCcarbeneP Frameworks for Facile Cooperative N2O Reduction
2018-07-10T14:51:34Z (GMT)
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A semiquantitative kinetic study correlates the rate of oxygen atom transfer from N<sub>2</sub>O to an iridium carbon double bond with the donor properties of six PC<sub>carbene</sub>P pincer ligand frameworks. Two new rigid, electron rich ligands are described and shown to be the most effective for rapid, selective reaction with N<sub>2</sub>O.<br>
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CC BY-NC-ND 4.0