Selective oxidation of glycerol to dihidroxyacetone (DHA): a comparison between neocuproine-Pd(OAc)2 based catalyst and an its dimeric form

27 September 2017, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The behaviour of two different organometallic complexes based on Pd were examined in depth with the aim to obtain the selective oxidation of glycerol to 1,3-dihydroxyacetone (DHA). An high glycerol conversion (93.5%) was obtained in a acetonitrile/water mixture in the presence of oxygen as a terminal oxidant.

Keywords

Organometallic compounds
DHA synthesis
glycerol
Homogeneous-Heterogeneous Reactions
Chemistry

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