Grand canonical rate theory for electrochemical and electrocatalytic systems I: General formulation and proton-coupled electron transfer reactions

2020-03-27T05:33:54Z (GMT) by Marko Melander
A generally valid rate theory at fixed potentials is developed to treat electrochemical and electrocatalytic potential-dependent electron, proton, and proton-coupled electron reactions. Both classical and quantum reactions are treated. The applicability and new information obtained from the theory is demonstrated for the gold catalyzed acidic Volmer reaction.