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Cross-Coupling Polymerization at Iodophenyl Thin Films Prepared by Spontaneous Grafting of a Diazonium Salt

preprint
revised on 14.02.2020 and posted on 17.02.2020 by Nicholas Marshall, Andres Rodriguez
Development of a method for the surface-initiated Kumada cross-coupling polymerization based on 4-iodophenyldiazonium salt thin films. Studies of the kinetics of chain termination and polymer film growth, and use of this method to make polythiophene brushes.

Funding

RISE, USC OVPR 2019

History

Email Address of Submitting Author

nicholasm@usca.edu

Institution

University of South Carolina Aiken

Country

United States of America

ORCID For Submitting Author

0000-0001-8048-0857

Declaration of Conflict of Interest

The authors declare no conflicts.

Version Notes

Version 2 / Revision 1, after one round of peer review. Many experiments added, including and especially XPS of PT films and kinetics of catalyst transfer.

Exports