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Chemical Availability of Bromide Dictates CsPbBr3 Nanocrystal Growth

submitted on 05.05.2019 and posted on 06.05.2019 by Je-Ruei Wen, Benjamin Roman, Freddy Rodriguez Ortiz, Noel Mireles Villegas, Nicholas Porcellino, Matthew Sheldon
Lack of detailed understanding of the growth mechanism of CsPbBr3 nanocrystals has hindered sophisticated morphological and chemical control of this important emerging optoelectronic material. Here, we have elucidated the growth mechanism by slowing the reaction kinetics. When 1-bromohexane is used as an alternative halide source, bromide is slowly released into the reaction mixture, extending the reaction time from ~3 seconds to greater than 20 minutes. This enables us to monitor the phase evolution of products over the course of reaction, revealing that CsBr is the initial species formed, followed by Cs4PbBr6, and finally CsPbBr3. Further, formation of monodisperse CsBr nanocrystals is demonstrated in a bromide-deficient and lead-abundant solution. The CsBr can only be transformed into CsPbBr3 nanocubes if additional bromide is added. Our results indicate a fundamentally different growth mechanism for CsPbBr3 in comparison with more established semiconductor nanocrystal systems and reveal the critical role of the chemical availability of bromide for the growth reactions.


Gordon and Betty Moore Foundation, GBMF6882

Welch Foundation, A-1886


Email Address of Submitting Author


Texas A&M University


United States

ORCID For Submitting Author


Declaration of Conflict of Interest

no conflict of interest