A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidative Couplings

2019-08-30T15:11:32Z (GMT) by Ayham Abazid Boris Nachtsheim
A triazole-substituted chiral aryl iodide is described as an efficient catalyst for a variety of diverse oxidative coupling reactions such as the Kita-spirocyclization, phenol-dearomatizations, alpha-oxygenations and oxidative rearrangements. Structures of the in situ oxidized hydroxy(tosyloxy)iodoarenes are discussed based on DFT-calculations.