A New Atomic Deformation Constraint Rule and Its Application
weicheng zeng
10.26434/chemrxiv.5857875.v1
https://chemrxiv.org/articles/A_New_Atomic_Deformation_Constraint_Rule_and_Its_Application/5857875
<p>A new principle of steady state of atoms in heteronuclear diatomic molecules based on constraint rule is proposed. Each atom in a heteronuclear diatomic molecule is described by three parameters a, b and ζand the atoms are the most stable when the value ζa/b is constant(2.601824). This model has one free parameter which was fitted by the graphical method.The calculated dissociation energy are in good agreement with the known experimental values.</p>
2018-02-06 16:45:41
Isoelectronic ionization energy
graphical method
New physical constant
Critical points
constraint rule